Title :
Phtalocyanine based integrated gas sensor
Author :
Moldovan, Carmen ; Hinescu, Lavinia ; Iosub, Rodica ; Hinescu, Mihail ; Nisulescu, Mihai ; Firtat, Bogdan ; Modreanu, Mircea ; Dascalu, Dan ; Voicu, Victor ; Tarabasanu, Cornel
Author_Institution :
Nat. Inst. for R&D in Microtechnol., Bucharest, Romania
Abstract :
This paper presents the layout and the technological steps for an interdigitally integrated capacitor used for gas detection. Silicon micromachining technology is applied for manufacturing the sensor substrate. The sensitive layer used is phthalocyanine (Pc) deposed by EDL (evaporated dyes layers technique). Many solutions were found using the phthalocyanine derivatives deposition technique. Considering the different sensitivities of phthalocyanines derivatives, we obtained different gas sensors. The copper phthalocyanine (Cu Pc) and nickel phthalocyanine (Ni Pc) have been investigated for NOx detection. The measurement of sensors for NOx and NH3 detection are presented as concentration versus impedance. The microsensor testing structures deposited with phthalocyanines were investigated by impedance measurements in a vacuum chamber controlled by a gas analyzer. The measurements were made at room temperature but a medium temperature is applied (< 200°C) after measurement, for cleaning the material in order to reuse the sensor. The sensor is integrated, MOS compatible, cheap, easy to use and has low power consumption.
Keywords :
capacitive sensors; chemical variables measurement; gas sensors; integrated circuit manufacture; integrated circuit measurement; low-power electronics; micromachining; microsensors; organic compounds; vacuum deposition; 20 degC; 200 degC; EDL deposition; MOS compatible/low power sensors; NH3; NH3 detection; NOx; NOx detection; Si; concentration/impedance measurements; copper phthalocyanine; evaporated dyes layers techniques; gas analyzers; gas detection interdigitally integrated capacitors; gas sensors; medium temperature material cleaning phase; nickel phthalocyanine; phtalocyanine based integrated gas microsensors; phthalocyanine derivatives; phthalocyanine layer sensitivity; sensor reuse; silicon micromachining technology; vacuum chambers; Capacitors; Copper; Gas detectors; Impedance measurement; Manufacturing; Micromachining; Microsensors; Nickel; Silicon; Temperature sensors;
Conference_Titel :
Semiconductor Conference, 2002. CAS 2002 Proceedings. International
Print_ISBN :
0-7803-7440-1
DOI :
10.1109/SMICND.2002.1105800