Title :
Shunt types in multicrystalline solar cells
Author :
Breitenstein, O. ; Rakotoniaina, J.P. ; Neve, S. ; Al Rifai, M.H. ; Werner, Michael
Author_Institution :
Max-Planck-Inst. of Microstructure Phys., Halle, Germany
Abstract :
Nine different types of shunts have been found in state of the art multicrystalline solar cells by lock-in thermography and identified by SEM-investigation (incl. EBIC), TEM and EDX. These shunts differ by the type of their I-V characteristic (linear or non-linear) and by their physical origin. Six shunt types are process-induced, and three are caused by grown-in defects of the material. The most important process-induced shunts are residues of the emitter at the edge of the cells, cracks, recombination sites at the cell edge, Schottky type shunts below grid lines, scratches, and aluminum particles at the surface. The material-induced shunts are strong recombination sites at grown-in defects (e.g. metal-decorated small-angle grain boundaries), grown-in macroscopic SiN inclusions, and inversion layers crossing the wafer (e.g. carbon-induced).
Keywords :
EBIC; X-ray chemical analysis; cracks; elemental semiconductors; grain boundaries; inclusions; inversion layers; scanning electron microscopy; silicon; solar cells; surface recombination; transmission electron microscopy; EBIC; EDX; I-V characteristic; SEM; Schottky type shunt; Si; TEM; aluminum particles; cell edge; crack; grain boundaries; grown-in defect; inclusions; lock-in thermography; multicrystalline solar cell; recombination site; scratches; shunt;
Conference_Titel :
Photovoltaic Energy Conversion, 2003. Proceedings of 3rd World Conference on
Conference_Location :
Osaka, Japan
Print_ISBN :
4-9901816-0-3