Title :
High rate growth of micro-crystalline silicon by microwave-PECVD
Author :
Soppe, W.J. ; Biebericher, A.C.W. ; Devilee, C. ; Donke, H. ; Schlemm, H.
Author_Institution :
ECN Solar Energy, Petten, Netherlands
Abstract :
A high rate deposition method for growth of /spl mu/c-Si is presented. The deposition method is based on plasma enhanced CVD, using a linear microwave source. Homogeneous depositions of /spl mu/c-Si over an area with a larger width than 40 cm, and with deposition rates of more than 1 nm/s are achieved, using H/sub 2/ and SiH/sub 4/ as precursor gases. Dilution with Ar helps to obtain a more stable plasma at low process pressures, but does not improve the crystallinity of the layers. /spl mu/c-Si is grown for SiH/sub 4//H/sub 2/ ratios up to 0.2; for larger ratios the layers become amorphous. We varied the deposition temperature between 100/spl deg/C and 300/spl deg/C and were able to grow microcrystalline layers in the entire temperature range with growth rates larger than 0.6 nm/s. FTIR measurements show that the layers incorporate oxygen after deposition; this is due to porosity of the layers.
Keywords :
Fourier transform spectra; amorphous semiconductors; dark conductivity; elemental semiconductors; infrared spectra; plasma CVD; porosity; semiconductor growth; semiconductor thin films; silicon; 100 to 300 degC; FTIR measurements; Si; crystallinity; dark conductivity; high growth rate; homogeneous depositions; linear microwave source; microcrystalline layers; microcrystalline silicon; microwave PECVD; oxygen incorporation; plasma enhanced CVD; porosity; precursor gases; semiconductor growth; semiconductor thin films;
Conference_Titel :
Photovoltaic Energy Conversion, 2003. Proceedings of 3rd World Conference on
Conference_Location :
Osaka, Japan
Print_ISBN :
4-9901816-0-3