Title :
Ring closing metathesis in the synthesis of sultones
Author :
Karsch, Sandra ; Metz, Peter
Author_Institution :
Institut of Org. Chem., Dresden Univ. of Technol., Germany
fDate :
26 June-3 July 2004
Abstract :
Unsatured sultones with normal, medium and large ring sizes were efficiently synthesized by ring closing metathesis (RCM) of sulfonates. The resulting α,β-unsaturated sultones act as dienophils in intermolecular Diels-Alder reactions. A first cyclic sulfate formation through RCM has been discovered.
Keywords :
catalysis; organic compounds; reaction kinetics; α,β-unsaturated sultones; cyclic sulfate formation; dienophils; intermolecular Diels-Alder reactions; ring closing metathesis; Chemical technology; Chemistry; Nitrogen;
Conference_Titel :
Science and Technology, 2004. KORUS 2004. Proceedings. The 8th Russian-Korean International Symposium on
Print_ISBN :
0-7803-8383-4
DOI :
10.1109/KORUS.2004.1555531
