Title :
PA 6/EPDM blends for electrical insulations. Preliminary characterization
Author :
Caramitu, Alina Ruxandra ; Zaharescu, Traian ; Mitrea, Sorina ; Tsakiris, Violeta ; Marinescu, Virgil ; Avadanei, Lidia
Author_Institution :
Nat. Inst. for R&D in Electr. Eng. (ICPE-CA), Bucharest, Romania
Abstract :
Electrical insulations must have certain characteristics that recommend them for long term service. Apart from electrical features, preparation and mechanical characterization are the former steps for the development of peculiar materials. The present paper concerns the preparation and characterization of PA6/EPDM blends, whose formulations consist of the both polymers on four relative concentrations: 100/0, 90/10, 80/20 and 70/30. They were mixed in a plastograph, which ensures the material homogeneity. After preparation of chips and plates by specific thermal regime, they were subjected to several tests for detailed characterization of endurance. The mechanical behavior is characterized by tensile strength and compression resistance, which have proved the contribution of elastomer loading on the material plasticity. The X-ray diffraction and the SEM analysis demonstrated that the increase in the EPDM concentration the crystallinity level decreases, so that the toughening of polyamide by elastomer becomes effective during material manufacture. The comparison of thermal stability and the contribution of each blended components is presented based on nonisothermal chemiluminescence. Oxidation onset temperature is dropped down as the EPDM content growths. The blend endurances were evaluated starting from the ageing data obtained at three temperatures with corresponding degradation time according with CEI regulations. The present results highlight the possibility of the manufacture of cable insulation layers. The next stage of research will be devoted to electrical characterization.
Keywords :
X-ray diffraction; ageing; cable insulation; chemiluminescence; compressive strength; elastomers; materials testing; organic insulating materials; oxidation; plasticity; polymer blends; polymer structure; scanning electron microscopy; tensile strength; thermal stability; CEI regulation; EPDM content growth; PA6/EPDM blends; PDM concentration; SEM analysis; X-ray diffraction analysis; ageing data; cable insulation layer; chip preparation; compression resistance; crystallinity level; degradation time; elastomer; electrical characterization; electrical insulations; endurance characterization; ethylenepropylene-diene terpolymer; material homogeneity; material manufacture; material plasticity; mechanical behavior; nonisothermal chemiluminescence; oxidation onset temperature; plastograph; plate preparation; polyamide toughening; specific thermal regime; tensile strength; thermal stability; Indexes; Insulation; Oxidation; Plastics; Radiation effects; Thermal stability; elastomer; electrical insulation; polyamide;
Conference_Titel :
Advanced Topics in Electrical Engineering (ATEE), 2013 8th International Symposium on
Conference_Location :
Bucharest
Print_ISBN :
978-1-4673-5979-5
DOI :
10.1109/ATEE.2013.6563468