DocumentCode :
671219
Title :
Effect of catalyst on the fluorescence quenching of [Tris (4, 7-diphenyl-1, 10-phenanthroline) ruthenium (II) dichloride] for dissolved oxygen detection
Author :
Mahmud, Zulkifli ; Herman, Sukreen Hana ; Noor, Uzer Mohd ; Saharudin, Suhairi
Author_Institution :
Fac. of Electr. Eng., Univ. Teknol. MARA, Shah Alam, Malaysia
fYear :
2013
fDate :
25-27 Sept. 2013
Firstpage :
360
Lastpage :
362
Abstract :
We present the effect of the catalyst for sol-solution preparation of tris (4,7-diphenyl-1,10-phenanthroline) ruthenium(II) dichloride on the fluorescence quenching behavior. Two types of [Ru(dpp)3]2+ sol-solution were prepared with two types of catalyst namely acid hydrochloric (HCl) and ammonium hydroxide (NH4OH) and each of them was mixed with the dye-solution to form [Ru(dpp)3]2+ sol-gel solution. A polymer optical fiber tip was then coated by each of the solutions respectively by immersion method. A LED source at 460 nm was used as the excitation source and fluorescence emissions intensity was measured using a UV/VIS spectrometer. The results showed that the fiber optic coated with the solution using NH4OH gave higher fluorescence intensity.
Keywords :
catalysts; fibre optic sensors; gas sensors; organic compounds; oxygen; radiation quenching; ruthenium compounds; sol-gel processing; spectrochemical analysis; LED source; O; UV-vis spectrometer; acid hydrochloric catalyst; ammonium hydroxide catalyst; dissolved oxygen detection; excitation source; fluorescence emissions intensity; fluorescence quenching; immersion method; polymer optical fiber tip; sol-gel solution; sol-solution preparation; tris(4,7-diphenyl-1,10-phenanthroline) ruthenium(II) dichloride; wavelength 460 nm; Fluorescence; Optical fiber sensors; Optical fibers; Solids; Octyl-triEOS; dissolved oxygen sensor; dynamic quenching; hydrolytic condition;
fLanguage :
English
Publisher :
ieee
Conference_Titel :
Micro and Nanoelectronics (RSM), 2013 IEEE Regional Symposium on
Conference_Location :
Langkawi
Print_ISBN :
978-1-4799-1181-3
Type :
conf
DOI :
10.1109/RSM.2013.6706550
Filename :
6706550
Link To Document :
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