Title :
Radial junction nanopillar arrays textured n-type silicon solar cells
Author :
Pudasaini, Pushpa Raj ; Elam, David ; Ayon, Arturo A.
Author_Institution :
Dept. of Phys. & Astron., Univ. of Texas at San Antonio, San Antonio, TX, USA
Abstract :
We report the radial p-n junction nanopillar arrays textured n-type silicon solar cells, passivated by ALD deposited Al2O3. Low cost solution processible metal assisted chemical etching (MACE) and spin on dopant (SOD) techniques were used for the fabrication of proposed solar cells. The nanopillar arrays textured surface exhibits the excellent broadband omnidirectional antireflection properties, leading to AM1.5G spectrum weighted reflectivity as low as 4.37%. Despite having the high surface to volume ratio of the nanopillar arrays textured surface, we observed an open circuit voltage (VOC) and the short circuit current density (JSC) as high as 572mV and 29.9mA/cm2 respectively, which leads to the power conversion efficiency (PCE) in excess of 11.30%, for the optimized structure of the solar cells described herein. External quantum efficiency (EQE) measurements conforms the photocurrent enhancement contributed by the enhanced optical absorption in the optimized nanopillar arrays textured surface.
Keywords :
alumina; antireflection coatings; atomic layer deposition; current density; nanostructured materials; p-n junctions; photoconductivity; photoemission; short-circuit currents; solar cell arrays; surface texture; ALD deposition; AM1.5G spectrum weighted reflectivity; Al2O3; EQE measurements; MACE; PCE; SOD technique; broadband omnidirectional antireflection property; external quantum efficiency; metal assisted chemical etching; n-type silicon solar cell fabrication; open circuit voltage; optical absorption; photocurrent enhancement; power conversion efficiency; radial p-n junction nanopillar array textured surface; short circuit current density; spin on dopant; surface to volume ratio; voltage 572 mV; Aluminum oxide; Etching; Junctions; Photovoltaic cells; Silicon; Surface texture; anti-reflection; radial p-n junction; silicon nanopillar; solar cells; surface passivation;
Conference_Titel :
Photovoltaic Specialists Conference (PVSC), 2013 IEEE 39th
Conference_Location :
Tampa, FL
DOI :
10.1109/PVSC.2013.6744959