Characterization of electron-irradiated biaxially-oriented polypropylene films

Author

Hammoud, A.N. ; Laghari, J.R. ; Krishnakumar, B.

Author_Institution

Dept. of Electr. & Comput. Eng., State Univ. of New York, Buffalo, NY, USA

Volume

35

Issue

3

fYear

1988

fDate

6/1/1988 12:00:00 AM

Firstpage

1026

Lastpage

1029

Abstract

Post-radiation changes in the electrical and mechanical properties of capacitor-grade isotactic polypropylene films exposed to electron radiation were previously reported by the authors (ibid., vol.NS-34, no.6, p.1822-6, Dec. 1987). Based on the data obtained, it was suggested that crosslinking, chain scission and oxidative degradation were responsible for the radiation-induced changes in the film. In the present investigations, additional electrical characterizations that included the DC breakdown voltage and AC conductivity measurements were performed. Effects of the electron radiation on the physical and chemical properties were also evaluated to identify the actual degradation mechanisms. These studies included scanning electron microscopy, X-ray diffraction, infrared spectroscopy and sol-gel measurements. The results obtained confirm that crosslinking and chain scission of the polymer are responsible for the changes in the lower dose range, whereas oxidative degradation becomes predominant at higher dose levels

Keywords

X-ray diffraction examination of materials; electric breakdown of solids; electron beam effects; electronic conduction in insulating thin films; infrared spectra of organic molecules and substances; polymer films; scanning electron microscope examination of materials; AC conductivity; DC breakdown voltage; X-ray diffraction; capacitor-grade; chain scission; crosslinking; degradation mechanisms; electron-irradiated biaxially-oriented polypropylene films; infrared spectroscopy; oxidative degradation; scanning electron microscopy; sol-gel measurements; Capacitance measurement; Chemicals; Conductivity measurement; Degradation; Dielectric losses; Electrodes; Infrared spectra; Mechanical factors; Polymers; Scanning electron microscopy;

fLanguage

English

Journal_Title

Nuclear Science, IEEE Transactions on

Publisher

ieee

ISSN

0018-9499

Type

jour

DOI

10.1109/23.3697

Filename

3697