Title :
Electron spectroscopic imaging analysis of compositional inhomogeneity in CoCrTa longitudinal thin film media
Author :
Yahisa, Y. ; Kimoto, K. ; Usami, K. ; Matsuda, Y. ; Inagaki, J. ; Furusawa, K. ; Narishige, S.
Author_Institution :
Data Storage & Retrieval Syst. Div., Hitachi Ltd., Kanagawa, Japan
fDate :
11/1/1995 12:00:00 AM
Abstract :
The topographical nature of the compositional inhomogeneity in Co-17at.%Cr-5at.%Ta/Cr longitudinal thin film media deposited at different substrate temperature Ts, was analyzed using electron spectroscopic imaging. In the CoCrTa film deposited at high Ts, Cr segregates to the grain boundaries and intragrains, resulting in a two-dimensional network. The compositional variation grew as Ts became high. The concentration of the Cr enriched region was in the range 20-30 at.%, and that of the Cr depleted region was in the range 5-10 at.% for the sample Ts=270°C. A strain-free CoCrTa(112¯0) lattice spacing, which is probably related to the Cr concentration in the Co hexagonal matrix, decreased as Ts became high. This Cr segregation can reduce the exchange coupling between neighboring grains, resulting in low noise characteristics
Keywords :
chromium alloys; cobalt alloys; electron spectroscopy; grain boundary segregation; magnetic recording; magnetic thin films; tantalum alloys; 270 C; CoCrTa; CoCrTa longitudinal thin film media; compositional inhomogeneity; electron spectroscopic imaging; exchange coupling; grain boundary segregation; intragrain segregation; lattice spacing; noise; substrate temperature; topography; two-dimensional network; Chromium; Electrons; Grain boundaries; Image analysis; Lattices; Nonhomogeneous media; Spectroscopy; Sputtering; Substrates; Temperature;
Journal_Title :
Magnetics, IEEE Transactions on