Title :
Thermodynamic properties of samarium hexaboride
Author :
Macedo, Claudio A. ; Souza, Andre M C
Author_Institution :
Dept. de Fisica, Univ. Fed. de Sergipe, Brazil
fDate :
9/1/2002 12:00:00 AM
Abstract :
The semiconductor samarium hexaboride has its thermodynamic properties well known for more than thirty years. However the explanation of them from a unified and coherent physical model has remained as a theoretical challenge. We determine by means of numerical calculation the temperature dependence of the specific heat and magnetic susceptibility at low temperature using the Falicov-Kimball model and considering also the contribution of the background of magnetic moments of the located spins 4f5. The very good agreement of our results with the experimental data enhances the relevance of the fermionic dynamics represented by the itinerant electron model as an important part of the properties of SmB6.
Keywords :
band model of magnetism; chemical potential; heavy fermion systems; magnetic susceptibility; metal-insulator transition; mixed valence compounds; samarium compounds; specific heat; Falicov-Kimball model; SmB6; chemical potential; fermionic dynamics; grand canonical ensemble; heavy fermion semiconductor; indirect hybridization gap semiconductor; itinerant electron model; low temperature; magnetic moments; magnetic susceptibility; one-dimensional model; semiconductor-metal transition; specific heat; temperature dependence; thermodynamic properties; valence fluctuations; Electrons; Fluctuations; Magnetic materials; Magnetic moments; Magnetic susceptibility; Numerical analysis; Samarium; Semiconductor materials; Temperature dependence; Thermodynamics;
Journal_Title :
Magnetics, IEEE Transactions on
DOI :
10.1109/TMAG.2002.803134