Title :
Nonlinear optical properties of K2La(NO3)5.2H2O and K2 Ce(NO3)5.2H2O
Author :
Ebbers, Christopher A. ; DeLoach, Laura Davis ; Webb, Mark ; Eimerl, David ; Velsko, Stephan P. ; Keszler, Douglas A.
Author_Institution :
Lawrence Livermore Nat. Lab., CA, USA
fDate :
2/1/1993 12:00:00 AM
Abstract :
The harmonic generating properties of potassium lanthanum nitrate (KLN) and potassium cerium nitrate (KCN) are described. These crystals have much larger nonlinear coefficients than potassium dihydrogen phosphate (KDP) and are nearly noncritically phase matched at room temperature for Type I frequency doubling of 1.064-μm light, and for Type II doubling of light near 0.95 μm. Thus, these crystals are useful for generating blue-green light by frequency doubling high-power near-infrared lasers. The crystal growth of KLN and KCN are described by the three component phase diagrams. Crystallographic data for KCN that confirms its structural similarity to KLN are presented. The optical absorption spectra of the two materials are discussed, and the linear refractive indexes are given
Keywords :
cerium compounds; crystal growth from solution; infrared spectra of inorganic solids; lanthanum compounds; optical harmonic generation; optical materials; potassium compounds; refractive index; visible spectra of inorganic solids; 0.95 micron; 1.064 micron; 310 to 1100 nm; K2Ce(NO3)5; K2Ce(NO3)5.2H2O; K2Ce(NO3)5H2O; K2La(NO3)5; K2La(NO3)5.2H2O; K2La(NO3)5H2O; Type I frequency doubling; Type II doubling; blue-green light; crystal growth; crystallographic data; harmonic generating properties; high-power near-infrared lasers; linear refractive indexes; nearly noncritically phase matched; nonlinear coefficients; nonlinear optical properties; optical absorption spectra; phase diagrams; room temperature; solution growth; Cerium; Crystallography; Crystals; Lanthanum; Nonlinear optics; Optical frequency conversion; Optical harmonic generation; Optical refraction; Optical variables control; Temperature;
Journal_Title :
Quantum Electronics, IEEE Journal of