• DocumentCode
    885308
  • Title

    Plasma synthesis of ammonia with a microgap dielectric barrier discharge at ambient pressure

  • Author

    Bai, Mindong ; Zhang, Zhitao ; Bai, Xiyao ; Bai, Mindi ; Ning, Wang

  • Author_Institution
    Environ. Eng. Res. Inst., Dalian Maritime Univ., Liaoning, China
  • Volume
    31
  • Issue
    6
  • fYear
    2003
  • Firstpage
    1285
  • Lastpage
    1291
  • Abstract
    The plasma synthesis of ammonia has been studied in nitrogen-hydrogen plasma using a microgap dielectric barrier discharge at ambient pressure. With the new technology of dielectric layers, the high-energy electrons are obtained in a narrow discharge gap; meanwhile, N2 and H2 molecules are ionized and dissociated and a large number of free atoms, ions, and radicals are formed in a nonequilibrium plasma after inelastic collisions. The final product was mainly ammonia, and the yield of ammonia reaches 12500 ppm (1.25%). In this way, plasma synthesis of ammonia at ambient pressure is realized and a new method is provided for inorganic synthesis.
  • Keywords
    ammonia; discharges (electric); ionisation potential; plasma chemistry; plasma materials processing; H2; N2; N2-H2; NH3; ambient pressure; ammonia concentration; ammonia synthesis; ammonia yield; dielectric barrier discharge; high-energy electrons; narrow discharge gap; nitrogen-hydrogen plasma; nonequilibrium plasma process; plasma synthesis; Atomic measurements; Chemicals; Dielectrics; Electrons; Ionization; Iron; Plasma chemistry; Plasma temperature; Radio frequency; Surface discharges;
  • fLanguage
    English
  • Journal_Title
    Plasma Science, IEEE Transactions on
  • Publisher
    ieee
  • ISSN
    0093-3813
  • Type

    jour

  • DOI
    10.1109/TPS.2003.818761
  • Filename
    1264904