DocumentCode

905661

Title

Spin-Ordering Leading Magnetic Transition in Sulphur System $\\hbox {ACr}_{2}\\hbox {S}_{4}$ ( $\\hbox {A}=\</h1></div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>Author</span></div><div class='col-12 col-md-9 leftDirection leftAlign'><h2 class='mb-0 fw-semibold'>Son, Bae Soon ; Bae, Sung Hwan ; Kim, Sam Jin ; Kim, Chul Sung</h2></div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>Author_Institution</span></div><div class='col-12 col-md-9 leftDirection leftAlign'>Dept. of Phys., Kookmin Univ., Seoul</div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>Volume</span></div><div class='col-12 col-md-9 leftDirection leftAlign'>45</div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>Issue</span></div><div class='col-12 col-md-9 leftDirection leftAlign'>6</div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>fYear</span></div><div class='col-12 col-md-9 leftDirection leftAlign'>2009</div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>fDate</span></div><div class='col-12 col-md-9 leftDirection leftAlign'>6/1/2009 12:00:00 AM</div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>Firstpage</span></div><div class='col-12 col-md-9 leftDirection leftAlign'>2634</div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>Lastpage</span></div><div class='col-12 col-md-9 leftDirection leftAlign'>2636</div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>Abstract</span></div><div class='col-12 col-md-9 leftDirection leftAlign'>Magnetic structure of Fe<sub>1-x</sub>Zn<sub>x</sub>Cr<sub>2</sub>S<sub>4</sub> (0.1 les x les 0.9) has been studied with magnetic susceptibility, X-ray diffraction and Mossbauer spectra. The crystal structures are found to have a cubic spinel with space group Fd3m. The lattice constants decrease with increasing Zn concentrations. According to magnetic susceptibility measurements, Neel temperature (T<sub>N</sub>) decreases with increasing Zn concentrations from x=0.5 to 0.7, especially T<sub>N</sub> dramatically decreases from 105 K to 45 K. The magnetic ground state reveal transition from ferrimagnetic to anti-ferromagnetic behavior at x=0.7. It is interpreted that the order of magnetic ions between tetrahedral (A) site ion and octahedral (B) site ion is antiparallel. The Mossbauer spectra show asymmetrical shapes due to large electric quadrupole interaction, magnetic hyperfine field of samples decrease in ferrimagnetic behavior ranges and increase in antiferromagnetic behavior ranges at 4.2 K. The magnetic hyperfine field of all samples for Zn concentration x = 0.1, 0.3, 0.5, 0.7 and 0.9 are 156, 128, 116, 131 and 138 kOe, respectively. It is described that the magnetic dipole interaction was weakened as substituting Zn ions in replacement of Fe on A site.</div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>Keywords</span></div><div class='col-12 col-md-9 leftDirection leftAlign'>Mossbauer effect; Neel temperature; X-ray diffraction; antiferromagnetic materials; chromium compounds; crystal structure; exchange interactions (electron); ferrimagnetic materials; hyperfine interactions; iron compounds; lattice constants; magnetic structure; magnetic susceptibility; quadrupole interactions; space groups; zinc compounds; FeCr<sub>2</sub>S<sub>4</sub>; Mossbauer spectra; Neel temperature; X-ray diffraction; ZnCr<sub>2</sub>S<sub>4</sub>; crystal structures; electric quadrupole interaction; exchange interactions; ferrimagnetic-antiferromagnetic transition; ground state; lattice constants; magnetic dipole interaction; magnetic hyperfine field; magnetic structure; magnetic susceptibility; magnetic transition; space group; spin-ordering; MÖssbauer Spectroscopy; Magnetic structure transition; sulphur spinel;</div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>fLanguage</span></div><div class='col-12 col-md-9 leftDirection leftAlign'>English</div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>Journal_Title</span></div><div class='col-12 col-md-9 leftDirection leftAlign'>Magnetics, IEEE Transactions on</div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>Publisher</span></div><div class='col-12 col-md-9 leftDirection leftAlign'>ieee</div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>ISSN</span></div><div class='col-12 col-md-9 leftDirection leftAlign'>0018-9464</div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>Type</span></div><div class='col-12 col-md-9 leftDirection leftAlign'><h2 class='mb-0 fw-semibold'>jour</h2></div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>DOI</span></div><div class='col-12 col-md-9 leftDirection leftAlign'>10.1109/TMAG.2009.2018929</div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>Filename</span></div><div class='col-12 col-md-9 leftDirection leftAlign'>4957692</div></div> </li> <div class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center'><div class='col-12 col-md-3 fw-bold mb-2 mb-md-0'><span class='text-muted small'>Link To Document</span></div><div class='col-12 col-md-9 leftDirection leftAlign'><a class='text-break' href='https://search.isc.ac/dl/search/defaultta.aspx?DTC=49&DC=905661' target='_blank' rel=$ https://search.isc.ac/dl/search/defaultta.aspx?DTC=49&DC=905661