Title :
Optical and Electrical Diagnostics of a High-Frequency Glow–Arc Discharge and Its Application to the Synthesis of Carbon Nanofibers
Author :
Valdivia-Barrientos, R. ; Pacheco-Sotelo, J.O. ; Pacheco-Pacheco, Marquidia ; Ramos-Flores, Jose Fidel ; Cruz-Azocar, Aurelio ; de Lourdes Jimenez-Lopez, Maria ; Benitez-Read, J.S. ; Lopez-Callejas, R.
Author_Institution :
Inst. Tecnologico de Toluca, Toluca, Mexico
Abstract :
In this paper, a detailed diagnostic of an AC glow-to-arc discharge transition is presented. The behavior of the temporal evolution of voltage and current discharges is studied under an atmosphere of helium-methane. In order to determine the rotational temperature, an optical emission-spectroscopy analysis from glow-to-arc regime discharge is carried out, where the OH and bands, respectively, which are situated at 306.357 nm (A2Σ+, ν=0→X2Π, ν\´=0) and 516.52 nm (d3Πg, ν\´=0→a3Πu, ν"=0), are used. Several metallic atomic lines were used to calculate the electron temperature. The principal discharge parameters, such as temperature and electron density in the arc regime, are determined. As an application of this glow-arc discharge, the synthesis of carbon nanofibers is reported.
Keywords :
arcs (electric); carbon; electron density; glow discharges; high-frequency discharges; nanostructured materials; nanotechnology; plasma diagnostics; plasma flow; plasma materials processing; plasma temperature; AC glow- to-arc discharge transition; C; C - Element; C2 - Element; OH; OH - Binary; carbon nanofibers; current discharge temporal evolution; electrical diagnostics; electron density; electron temperature; high-frequency glow-arc discharge; metallic atomic lines; optical diagnostics; optical emission spectroscopy; rotational temperature; voltage discharge temporal evolution; Arc discharges; Atmosphere; Electrodes; Electrons; Glow discharges; Morphology; Plasma diagnostics; Stimulated emission; Temperature; Voltage; Carbon nanofibers (CNFs); UV–OH band; glow–arc; high-frequency discharge; swan band;
Journal_Title :
Plasma Science, IEEE Transactions on
DOI :
10.1109/TPS.2007.906137