High vibrational temperatures in optically-pumped CO2

A pulsed 4.3-μm CO₂ laser was used to optically pump mixtures of CO₂ and He, and create transient gain at 9 and 10 μm. A conventional continuous-wave CO₂ laser operating on both regular and sequence bands measures this transient gain, and determined the ν₃ (asymmetric stretching)-mode vibrational temperature T₃. The measured values of T ₃ are generally much higher than those attained in discharge-excited CO₂. It is shown that a Treanor distribution must be used to describe the populations in the ν₃ -mode when dilute mixtures of CO₂ in He are optically pumped to ν₃-mode temperatures of 3000 to 4000 K. Under these conditions the sequence-band gain coefficients are almost equal to those on the regular bands. The collisional relaxation of energy from the ν₃ mode shows evidence of fast V-T relaxation at high values of T₃, followed by a slower relaxation rate characteristic of the 00⁰1 population lifetime