Evidence for continuous visible chemical lasing from the fast near resonant energy transfer pumping of atomic sodium

Energy transfer from selectively formed metastable states of SiO is used to pump sodium-atom laser amplifiers at λ≈569 nm (4d²D-3p²P), λ≈616 nm (5s²S-3p² P), and λ≈819 nm (3d²D -3p²P). The a³Σ⁺ and b³Π states of SiO are generated in high yield from the Si+N₂O→SiO+N₂ reaction. The energy stored in the triplet states is transferred in a highly efficient collisional process to pump sodium atoms to their lowest excited 3d² D, 4d²D, and 5s²S states. Adopting a sequence in which high concentrations of silicon and sodium atoms are mixed and oxidized, a continuous amplification (gain condition) is monitored which suggests the creation of a population inversion among the receptor sodium-atom energy levels and forms the basis for full cavity oscillation on the Na4 d²D-3p²P transition at 569 nm