چكيده لاتين :
1-Introduction
Corundum (Al2O3) is one of the rare metamorphic minerals that its formation requires particular chemical condition (low SiO2 and high Al2O3) in combination with high temperature (Simonet et al., 2008). Therefore, one of the most critical cases in the study of corundum-bearing rocks is the accurate determination of protolith and metamorphic conditions (Yakymchuk and Szilas, 2018).
In the Broujerd area, Berthier et al. (1974) reported the corundum in migmatites for the first time. Despite the many studies in metamorphic rocks, these corundum-bearing rocks never reported in later works, until (Ghaffari, 2010) and then (Papi, 2015) again reported corundum-bearing rocks in the area and both concluded that they are a kind of migmatites, evidence of granulite facies metamorphism. Neither Berthier et al. (1974) nor Gaffari (2010) and Papi (2015) reported albitite rocks that are in direct relations with corundum-bearing rocks. Also differences between whole rock composition in migmatites and corundum-bearing rocks and its possible role in corundum formation, never discussed.
2-Materials and Methods
Different samples collected for petrographic studies and finally, five samples had chosen for whole rock analysis (Table 1). Bulk rock compositions of selected samples were determined using an X-ray fluorescence spectrometer at the Zarazma Co., Tehran, Iran. Chemical compositions of minerals were obtained using a JEOL W-EPMA JXA8900-R electron microprobe in the Institute of Earth Sciences, Academia Sinica, Taiwan, at an acceleration voltage of 15 kV, a current of 15 nA, and a beam size of 2 nm. (Droop, 1987). The method used for Recalculation of Fe as Fe3+ and Fe2+. All mineral abbreviations are from (Whitney and Evans, 2010).
3-General geology and field relations
Borujerd area located in Sanandaj-Sirjan Zone in the western part of Iran. Intrusive rocks, as main granitoids and rare norite, gabbro, and pegmatites, with NW – SE trend, injected along dominant schistosity in metapelites (Berthier et al., 1974), during middle Jurassic (175-170Ma; (Ahmadi-Khalaji et al., 2007; Mahmoudi et al., 2011). Contact metamorphism developed during magmatism, especially in the northern part of Broujerd batholith. Highest metamorphic grade restricted either to the northern part of granitoids or as large enclaves.
Migmatites in Ab-Bakhshan area, show one of the most significant outcrops and located between granitoids and hornfelses. Based on Fig. 1, albitites dikes injected in migmatites. In general, towards albitites, migmatites first start to metasomatized and formed metasomatized-migmatites, then corundum-bearing rocks will appear either in contact or inside albitites.
Migmatites are metatexite with the low-melt portion, generally with patchy structure. In petrographic studies, they include relatively uniform mineralogy: quartz, plagioclase and potassium feldspar are main minerals in the leucosomes with granoblastic texture, while biotite, cordierite, andalusite, sillimanites, spinel, and Fe-Ti oxides, are major minerals in mesosome, generally with lepidoblastic or grno-lepidoblastic texture. Their chemical composition (Table 1) with high Al2O3 and SiO2, and low alkali and calcium show that they have the pelitic origin.
Metasomatized migmatites in the field are the same as migmatites, but under the microscope, andalusite and sillimanites start to replace by sericites, and biotites with chlorite. Near the corundum-bearing rocks (based on Figure 1) all andalusite and sillimanites completely replaced by sericites, all biotites with chlorites and also, feldspars altered. Comparing to migmatites, they have higher SiO2 and less Al2O3 (Table 1).
Corundum-bearing rocks have different mineralogy. They mainly composed of corundum, chlorite, white mica (tin muscovites) and feldspar (albite), with rare rutile, ilmenite, and apatite. Albitites are mainly composed of albite (more than 80%) and quartz, sericites, potassium feldspars as minor minerals. Their chemical composition is entirely different from migmatites, with a low concentration of SiO2 and higher Al2O3 and MgO (Table 1). Albitites are deformed and make dikes and small patches in migmatites. They mainly composed of albite with rare muscovite, quartz, and k-feldspar. Their chemical composition is following high–Na plagioclases (Table 1.