Abstract :
This paper studied the influence of copper concentration, pH, temperature, and the ratio of solid to solution on desorption of Zn in the kaolin from Suzhou, China in a background solution of 0.01 M CaCl2 by batch extraction experiments. At 0, 5, 50, 100 mg/l Cu concentration, for each 0.5 increase in pH between about 1.80 and 3.04% desorption decreases 3.80, 13.87, 9.97, and 7.65%, respectively. The pH50 (pH at 50% Zn desorption) is found to follow the sequence: Cu (5 mg/l, pH50 = 2.60) < Cu (50 mg/l, pH50 = 2.70) < Cu (100 mg/l, pH50 = 2.95) < Cu (0 mg/l, pH50 = 10.65). The free energy change ((delta)G) values, the values of enthalpy change ((delta)H), and entropy change ((delta)S) have been calculated. There were no large differences in the desorption of Zn from 25 to 50 °C. The concentration of Zn in solution after desorption equilibrium increases and percent desorption decreases when the solid to liquid ratio increases from 0.025 to 0.2. The kaolin possibly cannot be used for the landfill clay liner.
