Author/Authors :
Barbara Cosimelli، نويسنده , , Domenico Spinelli، نويسنده , , Francesca Costanzo، نويسنده , , Domenica Tonelli، نويسنده , , Liliana Lamartina، نويسنده , , Maria Concetta Sarvà، نويسنده , , Renato Seeber، نويسنده ,
Abstract :
The electronic effect of some meta- or para-substituents on the reduction of the title compounds has been investigated. The reversible reduction potential values of these compounds have been evaluated by cyclic voltammetry at a mercury electrode in 0.1 M tetraethylammoniumtetrafluoroborate, dimethylsulfoxide solutions. The substituent effect depends on both its nature and its position. The reduction potential values of the derivatives studied have been correlated with the Hammett substituent constants.