Title of article :
Substituent effect on the redox potential of substituted (aryl)(2-nitrobenzo[b]thiophen-3-yl)amines
Author/Authors :
Barbara Cosimelli، نويسنده , , Domenico Spinelli، نويسنده , , Francesca Costanzo، نويسنده , , Domenica Tonelli، نويسنده , , Liliana Lamartina، نويسنده , , Maria Concetta Sarvà، نويسنده , , Renato Seeber، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Pages :
4
From page :
1857
To page :
1860
Abstract :
The electronic effect of some meta- or para-substituents on the reduction of the title compounds has been investigated. The reversible reduction potential values of these compounds have been evaluated by cyclic voltammetry at a mercury electrode in 0.1 M tetraethylammoniumtetrafluoroborate, dimethylsulfoxide solutions. The substituent effect depends on both its nature and its position. The reduction potential values of the derivatives studied have been correlated with the Hammett substituent constants.
Keywords :
Reduction potential , Linear free energy relations , structure–reactivity
Journal title :
Tetrahedron
Serial Year :
2001
Journal title :
Tetrahedron
Record number :
1081755
Link To Document :
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