Title of article
Studies towards the total synthesis of palauʹamine. Formation of 4,5-dihydropyrrole-2-carboxylate intermediates by alkene–enamide ring-closing metathesis
Author/Authors
Jason D. Katz، نويسنده , , Larry E. Overman، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
10
From page
9559
To page
9568
Abstract
A highly functionalized 4,5-dihydropyrrole-2-carboxylate is assembled by alkene–enamide ring-closing metathesis. Subsequent intramolecular azomethine imine dipolar cycloaddition provides a triazacyclopenta[cd]pentalene intermediate of potential use in a total synthesis of palauʹamine.
Keywords
Palauיamine , Ring-closing metathesis , 4 , 5-Dihydropyrrole-2-carboxylate , Azomethine imine cycloaddition , enamide
Journal title
Tetrahedron
Serial Year
2004
Journal title
Tetrahedron
Record number
1087167
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