Title of article
KHSO4-Mediated Condensation Reactions of tert-Butanesulfinamide with Aldehydes. Preparation of tert-Butanesulfinyl Aldimines
Author/Authors
Zhang، Min نويسنده , , Qin، Yong نويسنده , , Huang، Zhiyan نويسنده , , Wang، Yin نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-1333
From page
1334
To page
0
Abstract
Optically pure tert-butanesulfinyl aldimines 1 were prepared by direct condensation of chiral tert-butanesulfinamide 3 with aldehydes 2 in high yields in the presence of KHSO4. The main advantage of KHSO4 is that it is applicable to the condensation reactions of a variety of aldehydes, including electron deficient and electron rich (hetereo)aromatic aldehydes, as well as aliphatic aldehydes.
Keywords
tert-butanesulfinamide , ALDEHYDE , potassium hydrogen sulfate , condensation , tert-butanesulfinyl aldimines
Journal title
Synlett
Serial Year
2005
Journal title
Synlett
Record number
110451
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