Title of article :
Tishchenko Reaction Using an Iridium-Ligand Bifunctional Catalyst
Author/Authors :
Suzuki، Takeyuki نويسنده , , Yamada، Taichiro نويسنده , , Matsuo، Tomohito نويسنده , , Watanabe، Kazuhiro نويسنده , , Katoh، Tadashi نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
Tishchenko reaction of aldehydes in the presence of an amino alcohol-based Ir bifunctional catalyst was developed. The reaction proceeds with 1 mol% of the catalyst and 20-30 mol% of K2CO3 in acetonitrile at room temperature to give the corresponding dimeric esters in good yield.
Keywords :
Aldehydes , esters , hydrogen transfer , iridium catalyst , Tishchenko reaction
