Title of article :
Mechanosynthesis of γ-nitro dicarbonyl compounds via CaCl2-catalyzed Michael addition
Author/Authors :
Chunman Jia، نويسنده , , Da Chen، نويسنده , , Chunyan Zhang، نويسنده , , Qi Zhang، نويسنده , , Bennan Cao، نويسنده , , Zhendong Zhao، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2013
Abstract :
An efficient strategy for the mechanosynthesis of γ-nitro dicarbonyl esters has been developed. A CaCl2-catalyzed Michael reaction, conducted at room temperature, afforded nitroalkenes from malonates in a short reaction time and in high yields. In most cases, polymerized side-reactions are eliminated or minimized.
Keywords :
Mechanosynthesis , ?-Nitro carbonyl esters , Michael addition , Ball-milling
Journal title :
Tetrahedron
Journal title :
Tetrahedron
