Title of article
Room-Temperature Palladium-Catalyzed and Copper(I)-Mediated Coupling Reactions of Acid Chlorides with Boronic Acids under Neutral Conditions
Author/Authors
Nishihara، Yasushi نويسنده , , Takagi، Kentaro نويسنده , , Inoue، Yoshiaki نويسنده , , Fujisawa، Mamoru نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-2308
From page
2309
To page
0
Abstract
The palladium-catalyzed cross-coupling reactions of acid chlorides with arylboronic acids in the presence of copper(I) thiophene-2-carboxylate (CuTC) as an activator under strictly non-basic and mild reaction conditions afford the unsymmetrical ketones in moderate to excellent yields. A wide range of substrates bearing an electron-donating or an electron-withdrawing substituent on the aromatic ring is compatible.
Keywords
ketones , copper , cross-coupling reaction , PALLADIUM , Boronic acid
Journal title
Synlett
Serial Year
2005
Journal title
Synlett
Record number
110751
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