Title of article
Polymer-Supported IBX-Amide Reagents: Significant Role of Spacer and Additive in Alcohol Oxidation
Author/Authors
Kim، Duk-Ki نويسنده , , Chung، Woo-Jae نويسنده , , Lee، Yoon-Sik نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-2174
From page
2175
To page
0
Abstract
We found that the spacer and additive play a significant role in the oxidation of alkyl alcohols using polymer-supported IBXamide reagents. The introduction of the spacer between the polymer support and IBX-amide group improved the initial conversion rate (up to 60% conversion). Furthermore, various alcohol compounds, when reacted with IBX-amide resin in the presence of BF3·OEt2, were effectively converted into the corresponding aldehydes or ketones within 5-30 minutes in high purities (>94%) at room temperature.
Keywords
spacer , additive , IBX-amide resin
Journal title
Synlett
Serial Year
2005
Journal title
Synlett
Record number
110792
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