Abstract :
The sublimation enthalpy of cubane, a key reference material for force field and quantum mechanical computations, was measured by combining the vaporization enthalpy at T = 298.15 K to the sum of the fusion enthalpy measured at T = 405 K and a solid–solid phase transition that occurs at T = 394 K. The fusion and solid–solid phase transitions were measured previously. A sublimation enthalpy value of (55.2 ± 2.0) kJ mol−1 at T = 298.15 K was obtained. This value compares quite favorably the value obtained by comparing the sublimation enthalpy of similar substances as a function of their molar masses but is at odds with earlier measurements.
