Title of article :
Thermodynamic properties of three adamantanols in the ideal gas state
Author/Authors :
M.B. Charapennikau، نويسنده , , A.V. Blokhin، نويسنده , , G.J. Kabo، نويسنده , , V.M. Sevruk، نويسنده , , A.P Krasulin، نويسنده ,
Issue Information :
دوهفته نامه با شماره پیاپی سال 2003
Pages :
7
From page :
85
To page :
91
Abstract :
The enthalpies of sublimation and the saturated vapor pressure of 1-adamantanol (1-Adol), 2-adamantanol (2-Adol) and 2-methyl-2-adamantanol (2-Me-2-Adol) were measured. Thermodynamic functions of the compounds under study in the ideal gas state between 100 and 1000 K were calculated by the statistical thermodynamic methods. The sets of wave numbers of normal vibrations for adamantanols were obtained by semi empirical calculation (MINDO3 И MNDO/d). The experimental entropies for gaseous adamantanols and the calculated values were in the satisfactory agreement.
Keywords :
Enthalpy of sublimation , 1-Adamantanol , Saturated vapor pressure , 2-Adamantanol , 2-Methyl-2-adamantanol
Journal title :
Thermochimica Acta
Serial Year :
2003
Journal title :
Thermochimica Acta
Record number :
1196123
Link To Document :
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