Title of article :
Bridging bonding mode in a metal–pteridine complex. Synthesis and structural characterization of Pt2Cl4(Hmp)2 (Hmp=4-hydroxy-2-mercaptopteridine)
Author/Authors :
Tsun-Ren Chen*، نويسنده , , Ying-Yann Wu، نويسنده , , Chi-Phi Wu، نويسنده , , Jhy-Der Chen، نويسنده , , Ching-Wang Huang، نويسنده , , Tai-Chiun Keng، نويسنده , , Ju-Chun Wang، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2000
Abstract :
Reaction of PtCl2 with Hmp (Hmp=4-hydroxy-2-mercaptopteridine) afforded the unique platinum–pteridine complex Pt2Cl4(Hmp)2, in which the Hmp ligand bridges the metal centers through the pyrazine ring nitrogen atom and the sulfur atom in a neutral form. This bonding mode is in marked contrast to the usual O4,N5-chelation mode of the pteridine units found in all the other reported complexes.
Keywords :
Pteridine complexes , Platinum complexes , N–H---Pt interaction , Bridging bonding mode
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications