Title of article :
Structure of [2,6-bis(dimethylamino)methyl]phenyltin tribromide hydrate
Author/Authors :
Roman Jambor، نويسنده , , Ale? R??i?ka، نويسنده , , Jiri Brus، نويسنده , , Ivana Cisarova، نويسنده , , Jaroslav Hole?ek، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2001
Pages :
4
From page :
257
To page :
260
Abstract :
The reaction of the 2,6-bis[(dimethylamino)methyl]phenyllithium with tin(IV) bromide affords, after recrystallisation from toluene on the air, the organotin(IV) compound [SnBr3{2,6-(Me2NCH2)2C6H3}(H2O)], 3, in which the N,C,N-ligand is bounded to Sn atom through the aryl carbon atom and one of the NMe2 groups only, while the second NMe2 group is protonated by hydrogen from the water molecule. The crystal structure analysis has shown dimeric structure of this compound, with unusually Sn–O–H–Br hydrogen bridges. This compound was characterised by NMR spectroscopy in solution and in the solid state and X-ray structure analysis.
Keywords :
Organotin(IV) , N-ligand , hydrogen bonds , NMR-spectroscopy , X-ray diffraction
Journal title :
Inorganic Chemistry Communications
Serial Year :
2001
Journal title :
Inorganic Chemistry Communications
Record number :
1315046
Link To Document :
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