Title of article :
Synthesis, spectroscopic study and X-ray crystal structure of unsymmetrical bis(phosphine)-platinum complex, [PtCl2{η2-Ph2POCH2CH2N(CH3)PPh2]
Author/Authors :
Maravanji S. Balakrishna، نويسنده , , Robert McDonald، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2002
Pages :
5
From page :
782
To page :
786
Abstract :
The bis(phosphine), Ph2POCH2CH2N(CH3)PPh2 (1) reacts with [Pt(COD)Cl2] to give seven-membered cis-chelated complex 2. The complex was characterized by elemental analysis, IR, and NMR spectroscopic methods of which the 31P{1H} NMR data is very informative and allows the direct measure of the P–P coupling through metal centers otherwise can not be seen in the free ligand as the two phosphorus centers are five-bonds apart. The structure of the platinum(II) complex was determined by X-ray crystallography.
Keywords :
Through-metal coupling , Platinum complex , Unsymmetrical bis(phosphine) , Chelate
Journal title :
Inorganic Chemistry Communications
Serial Year :
2002
Journal title :
Inorganic Chemistry Communications
Record number :
1315682
Link To Document :
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