Title of article :
Macropolyhedral borane reaction chemistry: Reductive oligomerisation of terBuNC by anti-B18H22 to give the boron-coordinated {(terBuNHCH){terBuNHC(CN)}CH2:} carbene residue
Author/Authors :
Tomas Jelinek، نويسنده , , Colin A. Kilner، نويسنده , , Simon A. Barrett، نويسنده , , Bohumil ?t?br، نويسنده , , Mark Thornton-Pett، نويسنده , , John D. Kennedy، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
Reaction of terBuNC with anti-B18H22 in CH2ClCH2Cl gives [7-{(terBuNHCH){terBuNHC(CN)}CH2}-anti-B18H20] in which a reductive oligomerisation of the terBuNC residues has given the complex polynitrogen base {(terBuNHCH){terBuNHC(CN)}CH2:}, formally as a zwitterionic carbene attached to the macropolyhedral {B18H20} cluster.
Keywords :
X-ray structure , Macropolyhedral cluster , Isocyanide oligomer , Borane cluster , Carbene ligand , Polynitrogen base formation , NMR spectroscopy
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
