Title of article
New tin(II) and tin(IV) amidophenolate complexes
Author/Authors
Alexandr V. Piskunov، نويسنده , , Igor A. Aivaz’yan، نويسنده , , Georgii K. Fukin، نويسنده , , Evgenii V. Baranov، نويسنده , , Andrey S. Shavyrin، نويسنده , , Vladimir K. Cherkasov، نويسنده , , Gleb A. Abakumov، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
4
From page
612
To page
615
Abstract
Treatment of tin amalgam with 4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-iminobenzoquinone (imQ) in THF results in formation of bis-(4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-amidophenolato)tin(IV) tetrahydrofuranate (1). The exchange reaction of imQ dilithium derivative with tin dichloride dioxanate in THF solution produces bis-[(4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-amidophenolato)tin(II)] (2). Stannylene (2) reacts with imQ in THF to give 1. Structures of 1 and 2 were determined by X-ray analysis.
Keywords
o-iminoquinone , Amidophenolate , Stannylene , X-ray diffraction , TIN
Journal title
Inorganic Chemistry Communications
Serial Year
2006
Journal title
Inorganic Chemistry Communications
Record number
1317060
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