Title of article :
Ionothermal synthesis of a 3D Zn–BTC metal-organic framework with distorted tetranuclear [Zn4(μ4-O)] subunits
Author/Authors :
Ling Xu، نويسنده , , Eun-Young Choi، نويسنده , , Young-Uk Kwon، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2008
Pages :
4
From page :
1190
To page :
1193
Abstract :
A zinc metal-organic framework (MOF), [Zn4(BTC)2(μ4-O)(H2O)2], was synthesized with Zn(NO3)2 · 6H2O and H3BTC ligand (H3BTC = 1,3,5-benzenetricarboxylic acid) by ionothermal synthesis in 1-ethyl-3-methylimidazolium bromide ionic liquid as solvent. The compound features a 3-D architecture constructed by linking [Zn4(μ4-O)] subunits with BTC3− ligands. They are composed of two five-coordinated and two four-coordinated Zn ions, different from the [Zn4(μ4-O)] units of other MOFs. The effect of reaction conditions to the MOF structure is discussed.
Keywords :
Ionothermal synthesis , 1 , zinc , 3 , MOF , 5-Benzenetricarboxylic acid
Journal title :
Inorganic Chemistry Communications
Serial Year :
2008
Journal title :
Inorganic Chemistry Communications
Record number :
1317920
Link To Document :
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