Title of article :
18-Crown-6 as a linker for (imino ester)2Pt centers providing their assembly into 1D arrays via hydrogen bonding
Author/Authors :
Tatiana G. Chulkova، نويسنده , , Pavel V. Gushchin، نويسنده , , Matti Haukka، نويسنده , , Vadim Yu. Kukushkin، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2010
Abstract :
The platinum(II- and IV) complexes trans-[PtCln{HNdouble bond; length as m-dashC(OMe)Et}2] (n = 2, 4) were assembled with 18-crown-6 into novel 1D arrays by hydrogen bonding thus forming 1:1 associates. The crystal structure determinations revealed the presence of the N–H⋯O and the non-conventional weak CH⋯O interactions between the imino hydrogen and the methyl hydrogens, respectively, of trans-[PtCln{HNdouble bond; length as m-dashC(OMe)Et}2] and the oxygens of 18-crown-6.
Keywords :
Platinum , Supramolecular chemistry , 1D arrays , 18-Crown-6 , Imino ester ligand
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
