Title of article :
Synthesis, crystal structures and magnetic studies on the nickel(II) and manganese(II) complexes containing the 2-pyridyl methyl ketazine
Author/Authors :
Jing Xiang، نويسنده , , LinLin Zhao، نويسنده , , Ya LUO، نويسنده , , Zhong-Hua Yan، نويسنده , , Chun-Hong Wang، نويسنده , , Jun Zhang، نويسنده , , Fan Zhou، نويسنده , , Ping-Mei Yan، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2013
Abstract :
Two double helical compounds with a general cationic structure [MII2(L1)2(Cl)3]+ have been obtained by treatment of L1 (L1 = 2-pyridyl methyl ketazine) and hydrated MIICl2 in MeOH, which were isolated as a PF6- salt (Mdouble bond; length as m-dashNi, 1) and a ClO4− salt (Mdouble bond; length as m-dashMn, 2), respectively. They represent first examples of double helicates of diazine complexes containing pseudo octahedral-coordinated metal ions. Their crystal structures have been determined by X-ray crystallography and the corresponding magnetic properties have been investigated in detail.
Keywords :
Magnetic properties , Double helicate , Manganese(II) , Diazine ligand , Nickel(II)
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications