Title of article :
1,1′-Bis(diphenyloxophosphoryl)ferrocene (dpopf) as ligand in silver(I) complexes. Crystal structure of [Ag(dpopf)(PPh3)2]ClO4
Author/Authors :
M.Concepci?n Gimeno، نويسنده , , Peter G Jones، نويسنده , , Antonio Laguna، نويسنده , , Cristina Sarroca، نويسنده , , M.Dolores Villacampa، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2001
Pages :
5
From page :
89
To page :
93
Abstract :
The ligand 1,1′-bis(diphenyloxophosphoryl)ferrocene, dpopf, reacted with silver derivatives to afford mononuclear complexes, [Ag(OClO3)(dpopf)] (1), [Ag(dpopf)2]ClO4, [Ag(dpopf)(PPh3)]ClO4, or the dinuclear complex, [{Ag(PPh3)}2(dpopf)](ClO4)2. From 1, other three-, [Ag(dpopf)(SPPh3)]ClO4, and four-coordinated derivatives, [Ag(dpopf)(PPh3)2]ClO4 (6) [Ag(dpopf)(LL)]ClO4 [LL=bipy, (SPPh2)2CH2] were obtained by substitution reactions. The crystal structure of 6 was solved and revealed the expected distorted tetrahedral coordination at silver, with a ligand bite angle of 96.10(13)°.
Keywords :
Silver complexes , Ferrocene complexes , Diphosphine complexes , crystal structures
Journal title :
INORGANICA CHIMICA ACTA
Serial Year :
2001
Journal title :
INORGANICA CHIMICA ACTA
Record number :
1320771
Link To Document :
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