Title of article :
Synthesis and X-ray single crystal structures of copper(I) complexes: Cu(S2PiBu2)·(PMe3)3 and Cu(S2PiBu2)·(PPh3)2
Author/Authors :
M.Azad Malik، نويسنده , , C Byrom، نويسنده , , P OʹBrien، نويسنده , , M Motevalli، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2002
Pages :
4
From page :
245
To page :
248
Abstract :
Two new copper(I) complexes Cu(S2PiBu2)·(PMe3)3 (1) and Cu(S2PiBu2)·(PPh3)2 (2) have been synthesised and characterised by spectroscopic and X-ray crystallographic methods. Both compounds are monomers in the solid state where copper is four co-ordinate and the co-ordination geometry is based on a distorted tetrahedron. The dithiophosphinate ligand behaves as a monodentate in compound 1 and bidentate in compound 2. Compound 1 is the only example in Cu(I) complexes with a monodentate dithiophosphinate.
Keywords :
Monodentate , Copper(I) , Complexes , Dithiophosphinate , X-ray , Synthesis
Journal title :
INORGANICA CHIMICA ACTA
Serial Year :
2002
Journal title :
INORGANICA CHIMICA ACTA
Record number :
1321469
Link To Document :
بازگشت