Author/Authors :
Tong Ren، نويسنده , , Damon A. Parrish، نويسنده , , Jeffrey R. Deschamps، نويسنده , , Judith L. Eglin، نويسنده , , Guolin Xu، نويسنده , , Wei-Zhong Chen، نويسنده , , Martin H. Moore، نويسنده , , Terence L. Schull، نويسنده , , Steven K. Pollack، نويسنده , , R. Shashidhar، نويسنده , , A.P. Sattelberger، نويسنده ,
Abstract :
The reaction between Os2(OAc)4Cl2 and Hap (Hap is 2-anilinopyridine) under prolonged refluxing conditions resulted in a new Os2(III) compound, Os2(ap)4Cl2 (1). The molecular structure of 1 was determined from a single crystal X-ray diffraction study, which revealed an Os–Os bond length of 2.396[1] Å, and a cis-(2,2) arrangement of the ap ligands. Also reported are magnetic, electrochemical and spectroscopic properties of 1.
