Author/Authors :
Ram A. Lal، نويسنده , , Samhita Bhaumik، نويسنده , , Aka Lemtur، نويسنده , , Mahesh K. Singh، نويسنده , , Debjani Basumatari، نويسنده , , Sanjesh Choudhury، نويسنده , , Arjun De، نويسنده , , Arvind Kumar، نويسنده ,
Abstract :
The binuclear manganese (IV) [Mn2(Hsal)4(OH)4] (H2sal = salicylic acid) complex has been obtained from a complex reaction mixture in methanol consisting of Mn(II)(OAc)2 · 4H2O, GS ( a reagent obtained by refluxing glycine and salicylaldehyde in 1:1 molar ratio in methanol), monosodium salicylate and pyridine. The compound contains a distorted octahedral MnO6 coordination unit of potential importance to high oxidation state manganese bimolecules.
Keywords :
crystal structure , Salicylic acid , Maganese (IV) complex , Spectroscopic data