Title of article :
NMR characterization, dynamics and crystal structure of [2,2′-dipyridyl(bis-pyridine) palladium(II)]2+ and related cations
Author/Authors :
Archimede Rotondo، نويسنده , , Giuseppe Bruno، نويسنده , , Matteo Cusumano، نويسنده , , Enrico Rotondo، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2009
Pages :
7
From page :
4767
To page :
4773
Abstract :
Eight PdII complexes are chemically and structurally characterized by NMR and X-ray diffraction. Their common structural feature is the planar 2,2′-bipyridyl ligand (bipy) faced by variously substituted, vertical pyridines (n-Rpy). Dissymmetric Csn-Rpy lead, in solution, to syn and anti geometric isomers whose dynamic interconvertion can be either driven by pyridine rotation or reversible dissociation. Activation energy of the rotational motion is for Pd lower than Pt in accord with a weaker double bond character of Pd–Npy bond. The energetic barrier also owns a steric contribution which becomes dominant for 2-Mepy. Methyl bumping locks rotation and loosens Pd–Npy bond, triggering an alternative isomerization pathway.
Keywords :
crystal structure , NMR dynamics , Palladium square-planar complexes
Journal title :
INORGANICA CHIMICA ACTA
Serial Year :
2009
Journal title :
INORGANICA CHIMICA ACTA
Record number :
1327883
Link To Document :
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