Title of article :
Synthesis and characterization of a novel spring-like organotin complex containing guest benzene molecules
Author/Authors :
Zhang، نويسنده , , Junhong and Zhang، نويسنده , , Rufen and Wang، نويسنده , , Qingfeng and Ma، نويسنده , , Chunlin and Wang، نويسنده , , Daqi، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2010
Pages :
3
From page :
3616
To page :
3618
Abstract :
A novel spring-like organotin complex [(Ph3Sn)(C7H5ClNO2)]n·3C6H6 (1), has been synthesized by treatment of 6-chloro-3-pyridineacetic acid bis(triphenyltin)oxide on the condition of reflux. The complex was characterized by elemental analysis, FT-IR, NMR (1H, 13C and 119Sn) spectroscopy, and X-ray crystallography diffraction analysis. The structure analyses reveals that complex 1 is an 1D infinite chain linked by intermolecular Sn–O bonds, in which the guest benzene molecules are established in the cavity of this helical chain; all the tin atoms of complex 1 are five-coordinated.
Keywords :
Helical chain , Spring-like , Carboxylic acid , organotin
Journal title :
INORGANICA CHIMICA ACTA
Serial Year :
2010
Journal title :
INORGANICA CHIMICA ACTA
Record number :
1328660
Link To Document :
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