Title of article :
Ionothermal synthesis of the mixed-anion material, Ba3Cl4CO3
Author/Authors :
Patricia Leyva-Bailen، نويسنده , , Paz Vaqueiro، نويسنده , , Anthony V. Powell، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2009
Pages :
5
From page :
2333
To page :
2337
Abstract :
A low-temperature ionothermal method for the facile synthesis of the halide carbonate, Ba3Cl4CO3, in single-crystalline form has been developed. This has enabled the first determination of the crystal structure of this material to be carried out. Analysis of single-crystal X-ray diffraction data indicates that barium chloride carbonate crystallises in the orthorhombic space group Pnma (Z=4), with a=8.4074(11), b=9.5886(12), c=12.4833(15) Å (Rw=0.0392). It exhibits a complex structure in which a three-dimensional network is formed from cross-linking of chains of anion-centred octahedra that share faces.
Keywords :
crystal structure , Ionothermal synthesis , Mixed-anion compound , Halide carbonate
Journal title :
JOURNAL OF SOLID STATE CHEMISTRY
Serial Year :
2009
Journal title :
JOURNAL OF SOLID STATE CHEMISTRY
Record number :
1334062
Link To Document :
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