Self-organization in network glasses

The continuous random network model is widely used as a realistic description of the structure of covalent glasses and amorphous solids. We point out that in real glasses and amorphous materials, there are non-random structural elements that go beyond just simple chemical ordering. We propose that the network can self-organize at its formation or fictive temperature, and examine some of the possible consequences of such self-organization. We find that the absence of small rings can cause the mechanical threshold to change from a second order to a first order transition. We show that if stressed regions are inhibited in the network, then there are two-phase transitions and an intermediate phase that is rigid but stress-free. This intermediate phase is bounded by a second order transition on one side and a first order transition on the other. Recent experiments in chalcogenide glasses give evidence for this intermediate phase.