Title of article :
Stereoselective synthesis of α,β-unsaturated carboxylic acids from alkynes using the Fe(CO)5/t-BuOK/AcOH/CH2Cl2 reagent system
Author/Authors :
Mallesh Beesu، نويسنده , , Mariappan Periasamy، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2012
Abstract :
Reactive iron carbonyl species generated in situ using the Fe(CO)5/t-BuOK/CH3COOH/CH2Cl2 reagent system reacts with alkynes to give the corresponding α,β-unsaturated carboxylic acids after CuCl2·2H2O oxidation with some regio and stereoselectivity.
Keywords :
Hydrocarboxylation , Iron carbonyls , alkynes , ?-unsaturated carboxylic acids , ?
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
