Author/Authors :
Zhang، نويسنده , , Kai and Song، نويسنده , , Huisen and Sun، نويسنده , , Dongkai and Li، نويسنده , , Shunfen and Yang، نويسنده , , Xiangui and Zhao، نويسنده , , Yulong and Huang، نويسنده , , Wei-Zhe and Wu، نويسنده , , Yutang، نويسنده ,
Abstract :
A circulating slurry bubble reactor was developed to synthesise methanol via methyl formate from the gas mixture of carbon monoxide and hydrogen at low temperature. The strategy for designing and scaling up the bubble reactor involved a preliminary understanding of fluid dynamics in a cold model, continuous operations under industrial conditions and a parallel experiment in an autoclave. Per-pass syngas conversion was investigated during 100-h operations. The axial profile of solid catalyst concentration was measured just before the shutdown and the composition of liquid product was analysed after the shutdown. These results show that the circulating slurry bubble column will become a potential reactor for the commercial process of low-temperature methanol synthesis after the catalyst system has been improved.
Keywords :
Circulating slurry bubble reactor , Methyl formate , Syngas , Low-temperature , Methanol synthesis