Title of article :
Synthesis of α-trifluoromethyl unsaturated acids and derivatives
Author/Authors :
Tellier، نويسنده , , Frédérique and Audouin، نويسنده , , Max and Sauvêtre، نويسنده , , Raymond، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2002
Abstract :
A one pot synthesis of α-trifluoromethyl unsaturated acids via a [3,3]-sigmatropic rearrangement of allyl (or propargyl) fluorovinyl ethers is described. By proto- and iodolactonization, these acids lead to the corresponding trifluoromethylated lactones.
Keywords :
1 , 3 , 1 , 3 , ?-CF3 unsaturated acids , ?-CF3 furanones , Addition–elimination , 3]-Sigmatropic rearrangement , 3-Pentafluoropropene , 3 , ?-CF3 pyranones
Journal title :
Journal of Fluorine Chemistry
Journal title :
Journal of Fluorine Chemistry
