Title of article :
Hydrodefluorination of polyfluoro-2-naphthylamines by Zn in aqueous NH3: A correlation of the product distribution and the computationally predicted regioselectivity of the substrate radical anion fragmentation
Author/Authors :
Selivanova، نويسنده , , Galina A. and Reshetov، نويسنده , , Alexey V. and Beregovaya، نويسنده , , Irina V. and Vasil’eva، نويسنده , , Nadezhda V. and Bagryanskaya، نويسنده , , Irina Yu. and Shteingarts، نويسنده , , Vitalij D. Shteingarts، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2012
Abstract :
Hydrodefluorination of heptafluoro-2-naphthylamine and its less fluorinated analogues by zinc in aqueous ammonia has been explored with respect to the possibility to occur and to rationalize the product distribution in terms of the mechanism including formation and fragmentation of a polyfluoroarene radical anion.
Keywords :
Polyfluoro-2-naphthylamines , Hydrodefluorination , quantum-chemical calculations , X-ray analysis , CVA measurements
Journal title :
Journal of Fluorine Chemistry
Journal title :
Journal of Fluorine Chemistry
