Title of article
New structural units in molybdenum oxyfluoride chemistry
Author/Authors
Aldous، نويسنده , , David W. and Lightfoot، نويسنده , , Philip، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
6
From page
108
To page
113
Abstract
The solvothermal syntheses and crystal structures of five new molybdenum oxyfluorides are presented. These exhibit three novel structural units, each containing Mo in a reduced oxidation state: a dimeric [Mo2O4F2(C2H8N2)2] unit (Mo4+), a tetrameric [Mo4O8F10]6− unit (Mo5+) and an infinite chain [MoOF3]− unit (Mo4+). MoMo bonding is observed in each of the new building units.
Keywords
solvothermal synthesis , crystal structure , Metal–metal bonding , Molybdenum oxyfluoride
Journal title
Journal of Fluorine Chemistry
Serial Year
2012
Journal title
Journal of Fluorine Chemistry
Record number
1611917
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