Title of article
Synthesis of caryophyllose. Use of n-BuLi/Na-O-t-Bu in the coupling of highly functionalized ketones and dithioacetals
Author/Authors
Adinolfi، نويسنده , , Matteo and Barone، نويسنده , , Gaspare and Festa، نويسنده , , Pasquale and Guariniello، نويسنده , , Luigi and Iadonisi، نويسنده , , Alfonso، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
4981
To page
4985
Abstract
The C-4 branched monosaccharide caryophyllose 2a was synthesized by a convergent approach relying on the coupling of metalated dithioacetal 4b with ketone 3. Combined use of n-BuLi and t-Bu-ONa as deprotonation system for 4b turned out to be decisive for the success of this coupling.
Journal title
Tetrahedron Letters
Serial Year
2000
Journal title
Tetrahedron Letters
Record number
1638121
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