Author/Authors :
Ryu، نويسنده , , Ilhyong and Kreimerman، نويسنده , , Sergio and Niguma، نويسنده , , Tatsuro and Minakata، نويسنده , , Satoshi and Komatsu، نويسنده , , Mitsuo and Luo، نويسنده , , Zhiyong and Curran، نويسنده , , Dennis P، نويسنده ,
Abstract :
A simple free-radical method for the preparation of a variety of perfluorinated allylic compounds has been developed starting from perfluoroalkyl iodides and allyltins. Allyltributyltin, methallyltributyltin and crotyltributyltin all proved to be useful for the transformation. The desired perfluorinated allylic compound was conveniently isolated from the crude mixture by solid-phase extraction with fluorous reverse-phase silica (FRPS).
